The use of biomass derived solid fuels for electricity generation in combustion, gasification and pyrolysis plant has received increasing levels of interest for commercial operation in recent years. However, there are limited tools available which allow a prediction of the performance of these fuels during thermochemical transformation given an understanding of their original chemical structure.As such, this investigation has concentrated on the derivation of a simply utilised classification system able to predict a series of important fuel combustion characteristics given an understanding of both the organic and inorganic chemical and structural composition of any lignocellulosic biomass fuel. A prediction of volatile matter content and char yields during pyrolysis has been made using correlation with aromatic carbon, potassium and calcium contents using both thermogravimetric slow heating and simulated pulverised fuel (PF) entrained flow rapid heating.
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